www.issp.ac.ru RUS
 
 

 

Biography, publications

Rimma P. Shibaeva was born in Vladimir Region, Russia and was educatedat University in Nizhnii Novgorod (the former Gor'ky). She received her Ph.D degree in 1962 under supervision of academician N.Belov ( Institute of Crystallography , Moscow ).

Her doctoral work dealt with the crystal structures of silicates. From 1962 to 1990 she was Research Scientist at the Institute of Chemical Physics (Chernogolovka), where she carried out X-ray studies of the organic paramagnetics – stable nitroxyl radicals. From the end of the sixties she was involved in the team of Prof. I. Schegolev for investigating low–dimensional organic conductors. A lot of crystal structures of the radical anion salts of TCNQ and the radical cation salts of TTT,TSeT, DBTTF, BEDT-TTF etc. have been studied by Rimma Shibaeva. She received her Doctor of Sciences from Institute of Crystallography ( Moscow ) in 1978. In 1991 she moved to Institute of Solid State Physics , Russian Academy of Sciences (Chernogolovka), where she is working now as Lieder Scientific Researcher. She has held visiting positions at Laboratoire de Physique des Solides of the University of Paris XI (Orsay), the research group of Prof. P.Batail (1994) and at Graduate School of Science, Kyoto University , Japan , the research group of Prof. G.Saito (1998). She is author of more than 260 journal articles. Her carrent research interests focus on molecular functional materials, in particular, in the field of low–dimensional organic conductors and molecular magnets, understanding the relationship between their crystal structure and physical properties.

She is married. Her husband is a well known physicist from L.D.Landau Institute Prof. Yu.A. Bychkov.

 

Adress: Institute of Solid state Physics, RAS

142432, Chernogolovka, Moscow district, Russia

Fax: 7-496 –524-9701 (from abroud)

8-496-524-9701 (from Moscow and Moscow district)

8-496-524-9701 (from other Russian region and former USSR countries)

e-mail: shibaeva@issp.ac.ru

phones: 8-496-522-52-06 (from Moscow )-work

7-496-522-5206 (from abroud)-work

7-496-524-1251 (from abroud)-home

 

R.P.Shibaeva's publications ( 2007-2009)

1. First radical cation salts of 2,5-bis(1,3-dithian-2-ylidene)-1,3,4.6-tetrathiapentalene (BDA-TTP) with copper(II) metal complex anions: b-(BDA-TTP)4 Cu2 Cl6 and (BDA-TTP)2 CuCl4
A.V. Kazakova, N.D. Kushch, L.I. buravov, E.B. Yagubskii, S.V. Simonov, L.V. Zorina, S.S. Khasanov, R.P. Shibaeva, E. Canadell, J. Yamada and M. Umemiya
Russian Chemical Bulletin, Intern. Ed., v. 56, pp.1-7 (2007)

2.Structure and Magnetotransport Properties of the New Quasi-Two-Dimensional Molecular Metal b''-(BEDT-TTF)4 H3 O[ Fe(C2 O4 )3 ]·C6 H4 Cl2
L.V. Zorina, T.G. Prokhorova, S.V. Simonov, S.S. Khasanov, R.P. Shibaeva, A.I. Manakov, V.N. Zverev, L.I. Buravov, E.B. Yagubskii
JETP, 106, n.2, 347-354 (2008)

3. Spin Dynamics in the Crystals of (BEDO)6 [M(CN)6 ](H3 O, CH3 CN)2 , M=Fe,Cr
R.B. Morgunov, E.V. Kurganova,T.G. Prokhorova, E.B. Yagubskii, S.V. Simonov, R.P. Shibaeva
Russian Journal Fizika Tverdogo Tela, 50, n.4, 657-663(2008)

4. Bifunctional molecular metals based on BEDO-TTF radical cation salts with paramagnetic   [MIII (CN)6 ]3- anions, M=Fe, Cr, (Fe0.5 Co0.5 )
T.G. Prokhorova, S.V. Simonov, S.S. Khasanov, L.V. Zorina, L. I. Buravov, R. P. Shibaeva, E.B. Yagubskii,  R.B. Morgunov, D. Foltynowicz, R. Swietlik.
Synth. Metals, 158, 749-757 (2008)

5. Comparative study of magnetotransport properties and structural features of the organic superconductors k'-(BEDT-TTF)2 Cu[N(CN)2 ]X, where X=Cl, Br.
V. Zverev , A.Manakov, S. Khasanov , R. Shibaeva , N. Kushch , A. Kazakova ,  E. Yagubskii
Solid State Science, 10, i.12, 1749-1751 (2008)

6. Structural Phase Transition in Crystals of the Molecular Conductor   a'-(BDH-TTP)6 [Hg(SCN)3 ][Hg(SCN)4 ]
S.V. Simonov, L.V. Zorina, S.S. Khasanov, R.P. Shibaeva, E.Canadell 
Crystallography Reports,53,n..6, 1003-1008(2008)

7. A new hybrid molecular metal assembling a BEDT-TTF conducting network and the magnetic chain anion [Mn2 Cl5 (H2 O)5 ]-: a-(BEDT-TTF)2 [Mn2 Cl5 (H2 O)5 ]
L. V. Zorina, T. G. Prokhorova, S. S. Khasanov, S. V. Simonov, V. N. Zverev, A. V. Korobenko, A. V. Putrya, V. S. Mironov, E. Canadell, R. P. Shibaeva, E. B. Yagubskii
CrystEngComm., 11, 2102-2109 (2009)

8. Pseudopolymorphism, superstructure, and phase transitions in thecrystals of (BEDT-TTF)4 [MNOX5]2-xGx, molecular conductor family, where M = Os, Ru; X = Cl, Br; G is the solvent molecule
L.V. Zorina, S.V. Simonov, S.S. Khasanov, and R.P. Shibaeva
Journal of Structural Chemistry, V. 50, pp. S159-S165 (2009)

R.P.Shibaeva's publications ( 1999-2006 )

1. Molecular conductors with the common and robust building block (BEDT-TTF) 2 NP but different band filling: b''-(BEDT-TTF) 2 [NP], b'' -(BEDT-TTF) 3 [NP][EG] and b'' -(BEDT-TTF) 4 A[NP] 2 , where A= Na + , K + , Rb + , …; NP= [FeNO(CN) 5 ] 2- and EG= C 2 H 4 (OH) 2

S.V. Simonov, L.V. Zorina, S.S. Khasanov, R.P. Shibaeva, I.Yu. Shevyakova, L.I. Buravov, E.B. Yagubskii, E. Canadell

J.Mater. Chem., 16, pp.787-794 (2006)

2. Hybrid molecular metals based on BEDO-TTF salts with paramagnetic [CrNO(CN) 5 ] 3- and [M(CN) 6 ] 3- anions, M=Fe, Cr

A.Dubrovskii, T Prokhorova, N.Spitsina, A.Kasakova, N.Kushch, L.Buravov, S. Simonov, L.Zorina, S.Khasanov, R.Morgunov, O.Drozdova, Y. Tanimoto, R. Shibaeva, E. Yagubskii

J. Low. Temp. Phys. 142, 137-140 ( 2006 )

3. Ambient Pressure Superconductivity in k -(BEDT-TTF) 2 Cu[N(CN) 2 ]Cl Single Crystals

E.B. Yagubskii, N.D. Kushch, A.V. Kazakova, L.I. Buravov, V.N. Zverev, A.I. Manakov,

S.S. Khasanov, R.P. Shibaeva

J. Low. Temp . Phys . ( 2006)

4.  Localization of conductivity electrons and magnetic properties of ?"-(BEDT-TTF)4 NH4 [Me(C2 O4 )3 ]·DMF (Me = Cr3+ , Fe3+ ) molecular metals

R.B. Morgunov, R.P. Shibaeva, E.B. Yagubskii, Ò. Kato, Y. Tanimoto

ZhETF, 129, 139-149 (2006)

5.  Structural Features of Low-Dimensional Molecular Conductors – Representatives of New Hybrid Polyfunctional Materials: Review

R.P. Shibaeva, S.S. Khasanov,L.V. Zorina, S.V. Simonov

Crystallography Reports, 51, 949-967 (2006) [ Kristallografiya, 51, 1014-1033(2006)]

6.  Transport properties and structural features of the ambient-pressure superconductor k'-(BEDT- TTF)2 Cu[N(CN)2 ]Cl

V.N. Zverev, A.I. Manakov, S.S.  Khasanov, R.P. Shibaeva, N.D. Kushch, A.V. Kazakova, L.I. Buravov, E.B. Yagubskii, E.Canadell

PRB, 74, 104504/1-9 (2006)

7. Variety of molecular conducting layers in the family of radical cation salts based on BEDT-TTF with the metal mononitrosyl complex [OsNO(CN) 5 ] 2-

S.V. Simonov, I.Yu. Shevyakova, L.V. Zorina, S.S. Khasanov, L.I. Buravov, V.A. Emel'yanov, E. Canadell, R.P. Shibaeva, E.B. Yagubskii

J. Mater. Chem., 15, pp.2476-2488 ( 2005)

8. Superconductivity at Ambient Pressure in k-(BEDT-TTF)2 Cu[N(CN)2 ]Cl Crystals

E.B. Yagubskii, N.D. Kushch, A.V. Kazakova, L.I. Buravov, V.N. Zverev, A.I. Manakov, S.S. Khasanov, R.P. Shibaeva

JETP Letters, 82, 93-95 (2005) [Pis’ma Zh. Eksp. Teor. Fiz., 82, 99-102 (2005)]

9. Crystalline patterns and band structure dimensionality in a series of conducting Hybrids associating amide-functionalized EDT-TTF p -donors with the isosteric octahedral anions [FeNO(CN) 5 ] 2- and [M(CN) 6 ] 3- (M=Co, Fe)

L.V. Zorina, S.S. Khasanov, S.V. Simonov, R.P. Shibaeva, L.A. Kushch, L.I. Buravov, E.B. Yagubskii, S. Boudron, C. M e ziere, P. Batail, E.Canadell, P. Auban-Senzier

Synth. Metals, 155, pp.527-538 ( 2005)

10. The first BDH-TTP radical cation salts with mercuric counterions, k -(BDH-TTP) 4 [Hg(SCN) 4 ]C 6 H 5 NO 2 and a ' -(BDH-TTP) 6 [Hg(SCN) 3 ] [Hg(SCN) 4 ]

N.D. Kushch, A.V. Kazakova, L.I. Buravov, E.B. Yagubskii, S.V. Simonov, L.V. Zorina, S.S. Khasanov, R.P. Shibaeva, E.Canadell, Hua Song, Yun-ichi Yamada

Synth . Metals , 155, pp .588-594 ( 2005)

11. Magnetic Properties of localized spins and conducting electrons in  ?"-(BEDT-TTF)4 NH4 [Cr(C2 O4 )3 ]·DMF single crystals

R.B. Morgunov, A.A. Baskakov, L.R. Dunin-Barkovskii, L.V. Zorina, S.S. Khasanov, R.P. Shibaeva, T.G. Prokhorova, E.B. Yagubskii, T. Kato, Y. Tanimoto

Khimicheskaya Fizika, 24, 116-124 (2005)

12. Molecular Conductors and Superconductors Based on Trihalides of BEDT-TTF and Some of its Analogues

R.P. Shibaeva, E.B. Yagubskii

Chem.Rev. , 104, pp.5347-5378 ( 2004 )

13 .Localization of conduction-band electrons in b ”–(BEDT-TTF) 4 NH 4 [Cr(C 2 O 4 ) 3 ]·DMF single crystals

R.B. Morgunov, A.A. Baskakov, L.R. Dunin-Barkovskiy, S.S. Khasanov, R.P. Shibaeva, T.G. Prokhorova, E.B. Yagubskiy, T. Kato, Y. Tanimoto

J. Phys. IV France , 114, pp.335-337 ( 2004 )

14. Crystal Structure of new radical cation salt (DOET)4 [Fe(CN)5 NO]1.25 (C6 H5 Cl)0.75

L.V. Zorina, S.S. Khasanov, R.P. Shibaeva, I.Yu. Shevyakova, A.I. Kotov, E.B. Yagubskii

Kristallografiya, 49, 1113-1120 (2004)

15. Family of layer molecular conductors (BEDT-TTF)4 A[M(C2 O4 )3 ]Solv. With magnetic metaloxalate anions     

L.V. Zorina, S.S. Khasanov, R.P. Shibaeva

Vestnik of the Nizhegorodskii University named by N.I. Lobachevskii, seriya Fizika Tverdogo Tela,  1(7), 62-71 (2004)

16. Exploitation of the photochromic nitroprusside anion [FeNO(CN) 5 ] 2- as counterion for constructing molecular conductors: The first radical cation salts based on BDH-TTP and the amide functionalized derivatives of EDT-TTF

R. Shibaeva, S. Khasanov , L. Zorina, S. Simonov, I. Shevyakova, L. Kushch, L.Buravov, E. Yagubskii, S. Boudron , C. Meziere, P.Batail. E. Canadell, J.Yamada

J. Phys. IV France , 114, pp.481-485 ( 2004 )

17. New Organic metals based on BDH-TTP radical cation salts with the photochromic nitroprusside anion [FeNO(CN) 5 ] 2-

Shevyakova, L. Buravov, V. Tkacheva, L. Zorina, S. Khasanov, S. Simonov, J. Yamada, E. Canadell, R. Shibaeva, E. Yagubskii

Adv. Funct. Mater. , 14, pp. 660-668 ( 2004 )

18. Molecular Metals Based on BEDT-TTF Radical Cation Salts with Magnetic Metal Oxalates as Counterions: b "-(BEDT-TTF) 4 A[M(C2 O4)3 ]. DMF (A = NH 4 + , K + ; M = Cr III , Fe III )

T.G. Prokhorova, S.S. Khasanov, L.V. Zorina, L.I. Buravov, V.A. Tkacheva, A.A. Baskakov, R.B. Morgunov, M. Gener , E. Canadell, R.P. Shibaeva, E.B. Yagubskii

Adv.Funct.Mate. , 13, pp. 403-411 (2003 )

19. Structure-properties relationships in organic molecular conductors based on radical cation salts with octahedral metal complexes as counterions

R.P. Shibaeva, E.B. Yagubskii, E. Canadell, S.S. Khasanov, L.V. Zorina, L.A. Kushch, T.G. Prokhorova, I.Yu. Shevyakova, L.I. Buravov, V.A. Tkacheva, M. Gener

Synth.Metals , 133-134, pp.373-375 (2003 )

20. Crystal and electronic structures of the radical cation salt based on EDT-TTF and the photochromic nitroprusside anion, (EDT-TTF) 3 [Fe(CN) 5 NO]

L.V. Zorina, M. Gener, S.S. Khasanov, R.P. Shibaeva, E. Canadell , L.A. Kushch, E.B. Yagubskii

Synth. Metals , 128, pp.325-332 (2002 )

21. Molecular conductors based on radical cation hydrated halides: new crystal phase of the (BEDT-TTF) 3 Br 2·2H 2 O organic metal

S.S. Khasanov, L.V. Zorina, R.P. Shibaeva, S.I. Pesotskii, M.V. Kartsovnic, L.F. Veiros, E. Canadell

Synth. Metals, 131, pp.41-46 (2002 )

22. The First Mixed Valence Radical Cation Salts of BEDT-TTF with the Photochromic Metal Mononitrosyl Complexes [RuNOX 5 ] 2- (X=Br, Cl) as Counterions

I.Yu. Shevyakova, L.V. Zorina, S.S. Khasanov, L.I. Buravov, V.A. Tkacheva, R.P. Shibaeva, E.B. Yagubskii, E. Canadell

J.Solid State Chemestry, 168, pp.514-523 (2002 )

23. Radical Cation Salts of Tetrathiotetracene and Tetraselenotetracene with Photochromic Anion [FeNO(CN)5 ]2- .

I. Yu. Shevyakova, L.I. Buravov, L.A. Kushch, E.B. Yagubskii, S.S. Khasanov, L.V. Zorina, R.P. Shibaeva, N.V. Drichko,, I. Olejniczak

Russian Journal of Coordination Chemistry, 28,   487-495 (2002)

24. Interesting transport and magnetic properties in a new family of molecular materials based on the organic donor BET-TTF and the perrhenate anion

S.S. Khasanov, A. Perez-Benitez, B.Zh. Narymbetov, L.V. Zorina, R.P. Shibaeva, J. Singleton, A. Klehe, V.N. Laukhin, J. Vidal-Gancedo, J. Veciana, E. Canadel, C. Rovira

J. Mater. Chem., 12, pp.432-441, (2002)

25. New molecular Conductors Based on ETEDT-TTF Trihalides: From Single Crystals to Conducting Layers of Nanocrystals

M. Mas-Torrent, E. Ribera, V. Tkacheva, I. Mata, E. Molins, J. Vidal-Gancedo, S. Khasanov, L. Zorina, R. Shibaeva, R. Wojciechowski, J. Ulanski, K. Wurst, J. Veciana, V. Laukhin, E. Canadel, E. Laukhina and C. Rovira

Chem. Mater ., 14, pp.3295-3304, (2002)

26. First-order phase transition in the organic metal k -(BETS) 2 C (CN) 3

B.Zh. Narymbetov, E. Canadell, T. Togonidze, S.S. Khasanov, L.V. Zorina, R.P. Shibaeva, H. Kobayashi

J. Mater. Chem., 11, pp.332-336 (2001 )

27. Structures of (BEDT-TTF)-Based Organic Metals  with Photochromic Nitroprusside Anion, (BEDT-TTF)4 M[FeNO(CN)5 ]2 , where M = Na+ ,K+ ,NH4+ ,Tl+ ,Rb+ ,Cs+

S.S.Khasanov, L.V.Zorina, R.P.Shibaeva

Russian Journal of Coordination Chemistry, 27,  259-269 (2001)

28. Crystal Structure of Radical Cation Salt (BEDT-TTF)4 (GaCl4 )2 ?C6 H5 CH3

L.V. Zorina, S.S. Khasanov, B.Zh. Narymbetov, R.P. Shibaeva, A.I. Kotov, E.B. Yagubskii 

Crystallography Reports, 46, 219-224 (2001)

29. Comparative study of BEDT-TTF and Ni(dddt) 2 electroconducting salts with the HXO 4 (X = Se,S) anions

A.I. Kotov, L.I. Buravov, E.B. Yagubskii, S.S. Khasanov, L.V. Zorina, R.P. Shibaeva, E. Canadell

Synth.Metals, 124, pp.357-362 (2001)

30. Halides of BET-TTF: novel hydrated molecular metals

E. Laukhina, E. Ribera, J. Vidal-Gancedo, S. Khasanov, L. Zorina, R. Shibaeva, E. Canadell, V. Laukhin, M. Honold, M.-S. Nam , J. Singleton, J. Veciana, C. Rovira

Adv. Mater. , 12, pp.54-58 ( 2000 ).

31. A new organic conductor and a novel structural phase transition in the BEDT-TTF trihalide family

E. Laukhina, J. Vidal-Gancedo, S. Khasanov, V. Tkacheva, L. Zorina, R. Shibaeva, J. Singleton, R. Wojciechowski, J. Ulanski, V. Laukhin, J. Veciana, C. Rovira

Adv. Mater., 12 , pp.1205-1210 ( 2000 ).

32. A new stable organic metal based on the BEDO-TTF donor and the doubly charged nitroprusside anion, (BEDO-TTF) 4 [Fe(CN) 5 NO]

L.V. Zorina, S.S. Khasanov, R.P. Shibaeva, M. Gener, R. Rousseau, E. Canadell, L.A. Kushch, E.B. Yagubskii, O.O. Drozdova, K. Yakushi

J. Mater. Chem., 10, pp. 2017-2023 ( 2000 ).

33. Low-dimensional organic superconductors k -(BEDT-TTF) 2 Cu[N(CN) 2 X, where X = Br 0.5 Cl 0.5 , Br 0.7 Cl 0.3 and Br 0.9 I 0.1

R.P. Shibaeva, S.S. Khasanov, N.D. Kushch, E.B. Yagubskii, K. Boubekeur, P. Batail, E. Canadell

Supramplecular engeneering of synthetic metallic materials, ed. J. Veciana et al., Kluwer Academic Publishers, Netherlands, pp. 409-418, (1999)

34. Crystal structures of the new BETS-based organic metals: a -(BETS) 2 TlHg(SeCN) 4 and k -(BETS) 2 C (CN) 3

L.V. Zorina, B.Zh. Narymbetov, S.S. Khasanov, R.P. Shibaeva, N.D. Kushch, E.B. Yagubskii, A. Kobayashi, H. Kobayashi

Synth. Metals, 102, pp. 1735-1736 ( 1999 ).

35. Organic metals based on BEDT-TTF and BEDO-TTF chlorides

R.P. Shibaeva, S.S.Khasanov, B.Zh. Narymbetov, L.V. Zorina, A.V. Bazhenov, N.D. Kushch, E.B. Yagubskii, E. Canadell

Synth. Metals, 102, pp.1650 -1653 ( 1999 ).

36. Structural aspects of the phase transitions in (BEDO-TTF) 2 ReO 4· H 2 O

S.S. Khasanov, L.V. Zorina, R.P. Shibaeva, N.D. Kushch, E.B. Yagubskii, R. Rousseau, E. Canadell, Y. Barrans, J. Gaultier, D. Chasseau

Synth. Metals, 102, pp. 1853-1856 ( 1999 ).

37. A new family of charge transfer salts formed with the p-electron donor BET-TTF and ReO 4 - . Synthesis, X-ray structure and phisical properties

A. Perez-Benitez, C. Rovira, J. Veciana, J. Vidal-Gancedo, V.N. Laukhin, L.V. Zorina, S.S. Khasanov, B. Zh. Narymbetov, R.P. Shibaeva

Synth. Metals, 102, pp.1707 -1708 ( 1999 ).

38. New asymmetric p-electron donors yielding metallic charge transfer salts

C. Rovira, E. Ribera, J. Veciana, V.N. Laukhin, E. Molins, I. Mata, S.S. Khasanov, L.V. Zorina, B.Zh. Narymbetov, R.P. Shibaeva, K. Wurst

Synth. Metals, 102 , pp.2224-2227 ( 1999 ).

39. New family of low-dimensional organic metals based on the asymmetrical multisulfur donor ETEDT-TTF: transport and magnetotransport properties

V. Laukhin, E. Ribera, C. Rovira, J. Veciana, M. Gener, T. Togonidze, S. Khasanov, R. Shibaeva, W. Biberacher, K. Andres, M. Kartsovnik

Synth. Metals, 102, pp. 1772-1773 ( 1999 ).

40. Molecular metals based on radical cation salts of ET and some its analogues with the photochromic nitroprusside anion, [Fe(CN) 5 NO] 2-

L. Kushch, L. Buravov, V. Tkacheva, E. Yagubskii , L. Zorina, S. Khasanov, R. Shibaeva

Synth. Metals, 102, pp. 1646-1649 ( 1999 ).

41. Band structure and Fermi surface of the (BEDT-TTF) 4 M[Fe(CN) 5 NO] 2 (M = Na, K, Rb,...) molecular metals contaning the photochromic nitroprusside anion

M. Gener, E. Canadell, S.S. Khasanov, L.V. Zorina, R.P. Shibaeva, L.A. Kushch, E.B. Yagubskii

Solid State Commun., 111, pp. 329 -333 ( 1999 ).

42. New conducting molecular metal-polycarbonate bilayered composites: (ET) 2 IBr 2 /PC- and (BET) 2 IBr 2 /PC-films

E. Laukhina, V. Tkacheva, R. Shibaeva, S. Khasanov, C. Rovira, J. Veciana, J. Vidal-Gancedo, A. Tracz, J.K. Jeszka, A. Sproczynska, R. Wojciechowski, J. Ulanski, V. Laukhin

Synth. Metals, 102, pp. 1785-1786 ( 1999 ).

 
 

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