Biography, publications
Rimma P. Shibaeva was born in Vladimir Region, Russia and was educatedat
University in Nizhnii Novgorod (the former Gor'ky). She received
her Ph.D degree in 1962 under supervision of academician N.Belov
( Institute of Crystallography , Moscow ).
Her doctoral work dealt with the crystal structures of silicates.
From 1962 to 1990 she was Research Scientist at the Institute of
Chemical Physics (Chernogolovka), where she carried out X-ray studies
of the organic paramagnetics – stable nitroxyl radicals. From the
end of the sixties she was involved in the team of Prof. I. Schegolev
for investigating low–dimensional organic conductors. A lot of crystal
structures of the radical anion salts of TCNQ and the radical cation
salts of TTT,TSeT, DBTTF, BEDT-TTF etc. have been studied by Rimma
Shibaeva. She received her Doctor of Sciences from Institute of Crystallography
( Moscow ) in 1978. In 1991 she moved to Institute of Solid State
Physics , Russian Academy of Sciences (Chernogolovka), where she
is working now as Lieder Scientific Researcher. She has held visiting
positions at Laboratoire de Physique des Solides of the University
of Paris XI (Orsay), the research group of Prof. P.Batail (1994)
and at Graduate School of Science, Kyoto University , Japan , the
research group of Prof. G.Saito (1998). She is author of more than
260 journal articles. Her carrent research interests focus on molecular
functional materials, in particular, in the field of low–dimensional
organic conductors and molecular magnets, understanding the relationship
between their crystal structure and physical properties.
She is married. Her husband is a well known physicist from L.D.Landau
Institute Prof. Yu.A. Bychkov.
Adress: Institute of Solid state Physics, RAS
142432, Chernogolovka, Moscow district, Russia
Fax: 7-096 –524-9701 (from abroud)
8-2-524-9701 (from Moscow and Moscow district)
8-096-524-9701 (from other Russian region and former USSR countries)
e-mail: shibaeva@issp.ac.ru
phones: 7-522-5206 (from Moscow )-work
7-096-522-5206 (from abroud)-work
7-096-524-1251 (from abroud)-home (local: 2-1941)
R.P.Shibaeva's publications (
1999-2006 )
1. Molecular conductors with the common and robust
building block (BEDT-TTF) 2 NP but different band filling: b''-(BEDT-TTF) 2 [NP], b'' -(BEDT-TTF)
3 [NP][EG] and b'' -(BEDT-TTF) 4 A[NP] 2 , where A= Na + , K + , Rb + , …; NP=
[FeNO(CN) 5 ] 2- and EG= C 2 H 4 (OH) 2
S.V. Simonov, L.V. Zorina, S.S. Khasanov, R.P. Shibaeva, I.Yu.
Shevyakova, L.I. Buravov, E.B. Yagubskii, E. Canadell
J.Mater. Chem., 16, pp.787-794 (2006)
2. Hybrid molecular metals based on BEDO-TTF salts with paramagnetic
[CrNO(CN) 5 ] 3- and [M(CN) 6 ] 3- anions, M=Fe, Cr
A.Dubrovskii, T Prokhorova, N.Spitsina, A.Kasakova, N.Kushch,
L.Buravov, S.
Simonov, L.Zorina, S.Khasanov, R.Morgunov, O.Drozdova, Y. Tanimoto,
R. Shibaeva, E. Yagubskii
J. Low. Temp. Phys. ( 2006 )
3. Ambient Pressure Superconductivity in k -(BEDT-TTF) 2 Cu[N(CN)
2 ]Cl Single Crystals
E.B. Yagubskii, N.D. Kushch, A.V. Kazakova, L.I. Buravov, V.N.
Zverev, A.I. Manakov,
S.S. Khasanov, R.P. Shibaeva
J. Low. Temp . Phys . ( 2006)
4. Локализация электронов проводимости и магнитные
свойства молекулярных металлов ?"-(BEDT-TTF) 4 NH 4 [Me(C 2
O 4 ) 3 ]·DMF (Me = Cr 3+ , Fe 3+ )
Р.Б. Моргунов, Р.П. Шибаева, Э.Б. Ягубский, Т. Kato, Y. Tanimoto
ЖЭТФ , 129, 139-149 ( 2006 )
5. Структурные особенности низкоразмерных молекулярных проводников
– представителей новых гибридных полифункциональных материалов
Р.П. Шибаева, С.С. Хасанов, Л.В. Зорина, С.В.Симонов
Кристаллография ( 2006 )
6. Variety of molecular conducting layers in the family of radical
cation salts based on BEDT-TTF with the metal mononitrosyl complex
[OsNO(CN) 5 ] 2-
S.V. Simonov, I.Yu. Shevyakova, L.V. Zorina, S.S. Khasanov,
L.I. Buravov, V.A. Emel'yanov, E. Canadell, R.P.
Shibaeva, E.B. Yagubskii
J. Mater. Chem., 15, pp.2476-2488 ( 2005)
7. Сверхпроводимость при нормальном давлении в кристаллах k -( BEDT
- TTF) 2 Cu[N(CN) 2 ]Cl
Э.Б. Ягубский, Н.Д. Кущ, А.В. Казакова, Л.И. Буравов, В.Н. Зверев,
А.И. Манаков, С.С. Хасанов, Р.П. Шибаева
Письма в ЖЭТФ , 82, стр . 99-102 ( 2005 )
8. Crystalline patterns and band structure dimensionality in a series
of conducting Hybrids associating amide-functionalized EDT-TTF p
-donors with the isosteric octahedral anions [FeNO(CN) 5 ] 2- and
[M(CN) 6 ] 3- (M=Co, Fe)
L.V. Zorina, S.S. Khasanov, S.V. Simonov, R.P. Shibaeva, L.A.
Kushch, L.I. Buravov, E.B. Yagubskii, S. Boudron, C. M e
ziere, P. Batail, E.Canadell, P. Auban-Senzier
Synth. Metals, 155, pp.527-538 ( 2005)
9. The first BDH-TTP radical cation salts with mercuric counterions,
k -(BDH-TTP) 4 [Hg(SCN) 4 ]C 6 H 5 NO 2 and a ? -(BDH-TTP) 6 [Hg(SCN)
3 ] [Hg(SCN) 4 ]
N.D. Kushch, A.V. Kazakova, L.I. Buravov, E.B. Yagubskii, S.V.
Simonov, L.V. Zorina, S.S. Khasanov, R.P. Shibaeva, E.Canadell,
Hua Song, Yun-ichi Yamada
Synth . Metals , 155, pp .588-594 ( 2005)
10. Магнитные свойства локализованных моментов и электронов проводимости
в монокристаллах b ”–( BEDT - TTF ) 4 NH 4 [ Cr ( C 2 O 4 ) 3 ] ?
DMF
Р.Б. Моргунов, А.А. Баскаков, Л.Р. Дунин-Барковский, Л.В. Зорина, С.С.Хасанов, Р.П.Шибаева, Т.Г. Прохорова, Э.Б. Ягубский, Т.
Като, И.Танимото
Химическая физика, 24, 116-124 ( 2005 )
11. Molecular Conductors and Superconductors Based on Trihalides
of BEDT-TTF and Some of its Analogues
R.P. Shibaeva, E.B. Yagubskii
Chem.Rev. , 104, pp.5347-5378 ( 2004 )
12 .Localization of conduction-band electrons in b ”–(BEDT-TTF)
4 NH 4 [Cr(C 2 O 4 ) 3 ] ? DMF single crystals
R.B. Morgunov, A.A. Baskakov, L.R. Dunin-Barkovskiy, S.S. Khasanov,
R.P. Shibaeva, T.G. Prokhorova, E.B. Yagubskiy, T. Kato, Y. Tanimoto
J. Phys. IV France , 114, pp.335-337 ( 2004 )
13. Кристаллическая структура новой катион-радикальной соли (DOET)
4 [Fe(CN) 5 NO] 1.25 (C 6 H 5 Cl) 0.75
Л.В. Зорина, С.С. Хасанов, Р.П. Шибаева, И.Ю. Шевякова, А.И.
Котов, Э.Б. Ягубский
Кристаллография , 49, pp . 1113-1120 ( 2004 )
14. Семейство слоистых молекулярных проводников ( BEDT
- TTF ) 4 A [ M ( C 2 O 4 ) 3 ] Solv . с магнитными металлоксалатными
анионами
Л.В. Зорина, С.С. Хасанов, Р.П. Шибаева
Вестник Нижегородского университета им. Н.И. Лобачевского, серия
ФИЗИКА ТВЕРДОГО ТЕЛА , вып. 1(7), 62-71 ( 2004 )
15. Exploitation of the photochromic nitroprusside anion [FeNO(CN)
5 ] 2- as counterion for constructing molecular conductors: The first
radical cation salts based on BDH-TTP and the amide functionalized
derivatives of EDT-TTF
R. Shibaeva, S. Khasanov , L. Zorina, S. Simonov, I. Shevyakova,
L. Kushch, L.Buravov, E. Yagubskii, S. Boudron ,
C. Meziere, P.Batail. E. Canadell, J.Yamada
J. Phys. IV France , 114, pp.481-485 ( 2004 )
16. New Organic metals based on BDH-TTP radical cation salts with
the photochromic nitroprusside anion [FeNO(CN) 5 ] 2-
Shevyakova, L. Buravov, V. Tkacheva, L. Zorina, S. Khasanov,
S. Simonov, J. Yamada, E. Canadell, R. Shibaeva, E. Yagubskii
Adv. Funct. Mater. , 14, pp. 660-668 ( 2004 )
17. Molecular Metals Based on BEDT-TTF Radical Cation Salts with
Magnetic Metal Oxalates as Counterions: b "-(BEDT-TTF) 4 A[M(C
2 O 4 ) 3 ] ? DMF (A = NH 4 + , K + ; M = Cr III , Fe III )
T.G. Prokhorova, S.S. Khasanov, L.V. Zorina, L.I. Buravov, V.A.
Tkacheva, A.A. Baskakov, R.B. Morgunov, M. Gener , E. Canadell, R.P.
Shibaeva, E.B. Yagubskii
Adv.Funct.Mate. , 13, pp. 403-411 (2003 )
18. Structure-properties relationships in organic molecular conductors
based on radical cation salts with octahedral metal complexes as
counterions
R.P. Shibaeva, E.B. Yagubskii, E. Canadell, S.S. Khasanov, L.V.
Zorina, L.A. Kushch, T.G. Prokhorova, I.Yu. Shevyakova, L.I. Buravov,
V.A. Tkacheva, M. Gener
Synth.Metals , 133-134, pp.373-375 (2003 )
19. Crystal and electronic structures of the radical cation salt
based on EDT-TTF and the photochromic nitroprusside anion, (EDT-TTF)
3 [Fe(CN) 5 NO]
L.V. Zorina, M. Gener, S.S. Khasanov, R.P. Shibaeva, E.
Canadell , L.A. Kushch, E.B.
Yagubskii
Synth. Metals , 128, pp.325-332 (2002 )
20. Molecular conductors based on radical cation hydrated halides:
new crystal phase of the (BEDT-TTF) 3 Br 2 ? 2H 2 O organic metal
S.S. Khasanov, L.V. Zorina, R.P. Shibaeva, S.I. Pesotskii, M.V.
Kartsovnic, L.F. Veiros, E. Canadell
Synth. Metals, 131, pp.41-46 (2002 )
21. The First Mixed Valence Radical Cation Salts of BEDT-TTF with
the Photochromic Metal Mononitrosyl Complexes [RuNOX 5 ] 2- (X=Br,
Cl) as Counterions
I.Yu. Shevyakova, L.V. Zorina, S.S. Khasanov, L.I. Buravov,
V.A. Tkacheva, R.P. Shibaeva, E.B. Yagubskii, E. Canadell
J.Solid State Chemestry, 168,
pp.514-523 (2002 )
22. Катион-радикальные соли тетратиотетрацена и тетраселенотетрацена
с фотохромным анионом [ FeNO ( CN ) 5 ] 2- .
И.В. Шевякова, Л.И. Буравов, Л.А. Кущ, Э.Б. Ягубский, С.С. Хасанов,
Л.В. Зорина, Р.П. Шибаева, Н.В. Дричко, И. Олейнисчак
Координационная химия , 28, 520-529, (2002)
22. Interesting transport and magnetic properties in a new family
of molecular materials based on the organic donor BET-TTF and the
perrhenate anion
S.S. Khasanov, A. Perez-Benitez, B.Zh. Narymbetov, L.V. Zorina,
R.P. Shibaeva, J. Singleton, A. Klehe, V.N. Laukhin, J. Vidal-Gancedo,
J. Veciana, E. Canadel, C. Rovira
J. Mater. Chem., 12, pp.432-441, (2002)
23. New molecular Conductors Based on ETEDT-TTF Trihalides: From
Single Crystals to Conducting Layers of Nanocrystals
M. Mas-Torrent, E. Ribera, V. Tkacheva, I. Mata, E. Molins,
J. Vidal-Gancedo, S. Khasanov, L. Zorina, R. Shibaeva, R. Wojciechowski,
J. Ulanski, K. Wurst, J. Veciana, V. Laukhin, E. Canadel, E. Laukhina
and C. Rovira
Chem. Mater ., 14, pp.3295-3304, (2002)
24. First-order phase transition in the organic metal k -(BETS)
2 C (CN) 3
B.Zh. Narymbetov, E. Canadell, T. Togonidze, S.S. Khasanov,
L.V. Zorina, R.P. Shibaeva, H. Kobayashi
J. Mater. Chem., 11, pp.332-336 (2001 )
25. Structures of the organic metals based on BEDT-TTF with photochromic
nitroprusside anion, (BEDT-TTF) 4 M[FeNO(CN) 5 ] 2 , where M = Na
+ ,K + ,NH 4 + ,Tl + ,Rb + ,Cs +
S.S.Khasanov, L.V.Zorina, R.P.Shibaeva
Koordinatsionnaya khimiya 27, n.4, pp.283-293 (2001 )
26. Кристаллическая структура катион-радикальной соли ( BEDT - TTF
) 4 ( GaCl 4 ) 2 ? C 6 H 5 CH 3
Л.В. Зорина, С.С. Хасанов, Б.Ж. Нарымбетов, Р.П. Шибаева, A .И. Koтoв, Э.Б.Ягубский
Кристаллография 46, 259-264 (2001)
27. Comparative study of BEDT-TTF and Ni(dddt) 2 electroconducting
salts with the HXO 4 (X = Se,S) anions
A.I. Kotov, L.I. Buravov, E.B. Yagubskii, S.S. Khasanov, L.V.
Zorina, R.P. Shibaeva, E. Canadell
Synth.Metals, 124, pp.357-362 (2001)
28. Halides of BET-TTF: novel hydrated molecular metals
E. Laukhina, E. Ribera, J. Vidal-Gancedo, S. Khasanov, L. Zorina,
R. Shibaeva, E. Canadell, V. Laukhin, M. Honold, M.-S. Nam ,
J. Singleton, J. Veciana, C. Rovira
Adv. Mater. , 12, pp.54-58 ( 2000 ).
29. A new organic conductor and a novel structural phase transition
in the BEDT-TTF trihalide family
E. Laukhina, J. Vidal-Gancedo, S. Khasanov, V. Tkacheva, L.
Zorina, R. Shibaeva, J. Singleton, R. Wojciechowski, J. Ulanski,
V. Laukhin, J. Veciana, C. Rovira
Adv. Mater., 12 , pp.1205-1210 ( 2000 ).
30. A new stable organic metal based on the BEDO-TTF donor and the
doubly charged nitroprusside anion, (BEDO-TTF) 4 [Fe(CN) 5 NO]
L.V. Zorina, S.S. Khasanov, R.P. Shibaeva, M. Gener, R. Rousseau,
E. Canadell, L.A. Kushch, E.B. Yagubskii, O.O. Drozdova, K. Yakushi
J. Mater. Chem., 10, pp. 2017-2023 ( 2000 ).
31. Low-dimensional organic superconductors k -(BEDT-TTF) 2 Cu[N(CN)
2 X, where X = Br 0.5 Cl 0.5 , Br 0.7 Cl 0.3 and Br 0.9 I 0.1
R.P. Shibaeva, S.S. Khasanov, N.D. Kushch, E.B. Yagubskii, K. Boubekeur,
P. Batail, E. Canadell
Supramplecular engeneering of synthetic metallic materials, ed.
J. Veciana et al., Kluwer Academic Publishers, Netherlands, pp. 409-418, (1999)
32. Crystal structures of the new BETS-based organic metals: a -(BETS)
2 TlHg(SeCN) 4 and k -(BETS) 2 C (CN) 3
L.V. Zorina, B.Zh. Narymbetov, S.S. Khasanov, R.P. Shibaeva,
N.D. Kushch, E.B. Yagubskii, A. Kobayashi, H. Kobayashi
Synth. Metals, 102, pp. 1735-1736 ( 1999 ).
33. Organic metals based on BEDT-TTF and BEDO-TTF chlorides
R.P. Shibaeva, S.S.Khasanov, B.Zh. Narymbetov, L.V. Zorina, A.V.
Bazhenov, N.D. Kushch, E.B. Yagubskii, E. Canadell
Synth. Metals, 102, pp.1650 -1653 ( 1999 ).
34. Structural aspects of the phase transitions in (BEDO-TTF) 2
ReO 4 ? H 2 O
S.S. Khasanov, L.V. Zorina, R.P. Shibaeva, N.D. Kushch, E.B. Yagubskii,
R. Rousseau, E. Canadell, Y. Barrans, J. Gaultier, D. Chasseau
Synth. Metals, 102, pp. 1853-1856 ( 1999 ).
35. A new family of charge transfer salts formed with the p-electron
donor BET-TTF and ReO 4 - . Synthesis, X-ray structure and phisical
properties
A. Perez-Benitez, C. Rovira, J. Veciana, J. Vidal-Gancedo, V.N.
Laukhin, L.V. Zorina, S.S. Khasanov, B. Zh. Narymbetov, R.P. Shibaeva
Synth. Metals, 102, pp.1707 -1708 ( 1999 ).
36. New asymmetric p-electron donors yielding metallic charge transfer
salts
C. Rovira, E. Ribera, J. Veciana, V.N. Laukhin, E. Molins, I. Mata,
S.S. Khasanov, L.V. Zorina, B.Zh. Narymbetov, R.P. Shibaeva, K. Wurst
Synth. Metals, 102 , pp.2224-2227 ( 1999 ).
37. New family of low-dimensional organic metals based on the asymmetrical
multisulfur donor ETEDT-TTF: transport and magnetotransport properties
V. Laukhin, E. Ribera, C. Rovira, J. Veciana, M. Gener, T. Togonidze,
S. Khasanov, R. Shibaeva, W. Biberacher, K. Andres, M. Kartsovnik
Synth. Metals, 102, pp. 1772-1773 ( 1999 ).
38. Molecular metals based on radical cation salts of ET and some
its analogues with the
photochromic nitroprusside anion, [Fe(CN) 5 NO] 2-
L. Kushch, L. Buravov, V. Tkacheva, E. Yagubskii , L. Zorina, S.
Khasanov, R. Shibaeva
Synth. Metals, 102, pp. 1646-1649 ( 1999 ).
39. Band structure and Fermi surface of the (BEDT-TTF) 4 M[Fe(CN)
5 NO] 2 (M = Na, K, Rb,...) molecular metals contaning the photochromic
nitroprusside anion
M. Gener, E. Canadell, S.S. Khasanov, L.V. Zorina, R.P. Shibaeva,
L.A. Kushch, E.B. Yagubskii
Solid State Commun., 111, pp.
329 -333 ( 1999 ).
40. New conducting molecular metal-polycarbonate bilayered composites:
(ET) 2 IBr 2 /PC- and (BET) 2 IBr 2 /PC-films
E. Laukhina, V. Tkacheva, R. Shibaeva, S. Khasanov, C. Rovira,
J. Veciana, J. Vidal-Gancedo, A. Tracz, J.K. Jeszka, A. Sproczynska,
R. Wojciechowski, J. Ulanski, V. Laukhin
Synth. Metals, 102, pp. 1785-1786 ( 1999 ).
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